Hazora · Library
Guide 139 · ERG 2024
Guide 139 · Library · ERG 2024
- Guides
- 139
- UN/NA
- 29
- Edition
- ERG 2024
In ERG 2024, Guide 139 is titled “Substances - Water-Reactive (Emitting Flammable And Toxic Gases)”.
Guide 139 covers 29 UN/NA numbers and 39 material names in ERG 2024. None of them carries the letter P (139P). 17 are highlighted in green and listed in Table 1: UN/NA 1183 (Ethyldichlorosilane); UN/NA 1242 (Methyldichlorosilane); UN/NA 1295 (Trichlorosilane); UN/NA 1340 (Phosphorus pentasulfide, free from yellow and white phosphorus); UN/NA 1360 (Calcium phosphide); UN/NA 1390 (Alkali metal amides); UN/NA 1397 (Aluminum phosphide); UN/NA 1419 (Magnesium aluminum phosphide); UN/NA 1432 (Sodium phosphide); UN/NA 2011 (Magnesium phosphide); UN/NA 2012 (Potassium phosphide); UN/NA 2013 (Strontium phosphide); UN/NA 2806 (Lithium nitride); UN/NA 2965 (Boron trifluoride dimethyl etherate); UN/NA 2988 (Chlorosilanes, water-reactive, flammable, corrosive, n.o.s.); UN/NA 3385 (Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A)) and UN/NA 3386 (Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B)). 15 appear in Table 2 as water-reactive materials that produce toxic gases: UN/NA 1183 (Ethyldichlorosilane: HCl); UN/NA 1242 (Methyldichlorosilane: HCl); UN/NA 1295 (Trichlorosilane: HCl); UN/NA 1340 (Phosphorus pentasulfide, free from yellow and white phosphorus: H2S); UN/NA 1360 (Calcium phosphide: PH3); UN/NA 1390 (Alkali metal amides: NH3); UN/NA 1397 (Aluminum phosphide: PH3); UN/NA 1419 (Magnesium aluminum phosphide: PH3); UN/NA 1432 (Sodium phosphide: PH3); UN/NA 2011 (Magnesium phosphide: PH3); UN/NA 2012 (Potassium phosphide: PH3); UN/NA 2013 (Strontium phosphide: PH3); UN/NA 2806 (Lithium nitride: NH3); UN/NA 2965 (Boron trifluoride dimethyl etherate: HF) and UN/NA 2988 (Chlorosilanes, water-reactive, flammable, corrosive, n.o.s.: HCl).
The Spanish edition (GRE 2024) titles this guide “Sustancias - Reactivas con el Agua (emiten gases inflamables y tóxicos)”, and the French edition (GMU 2024) “Substances - Réagissant à l’eau (émettant des gaz inflammables et toxiques)”.
Material name
| UN/NA | Language | Material name |
|---|---|---|
| 1183 | EN | Ethyldichlorosilane |
| 1242 | EN | Methyldichlorosilane |
| 1295 | EN | Trichlorosilane |
| 1339 | EN | Phosphorus heptasulfide, free from yellow and white phosphorus |
| 1340 | EN | Phosphorus pentasulfide, free from yellow and white phosphorus |
| 1341 | EN | Phosphorus sesquisulfide, free from yellow and white phosphorus |
| 1343 | EN | Phosphorus trisulfide, free from yellow and white phosphorus |
| 1360 | EN | Calcium phosphide |
| 1390 | EN | Alkali metal amides |
| 1395 | EN | Aluminum ferrosilicon powder |
| 1397 | EN | Aluminum phosphide |
| 1408 | EN | Ferrosilicon |
| 1419 | EN | Magnesium aluminum phosphide |
| 1432 | EN | Sodium phosphide |
| 1433 | EN | Stannic phosphides |
| 1714 | EN | Zinc phosphide |
| 2011 | EN | Magnesium phosphide |
| 2012 | EN | Potassium phosphide |
| 2013 | EN | Strontium phosphide |
| 2806 | EN | Lithium nitride |
| 2830 | EN | Lithium ferrosilicon |
| 2965 | EN | Boron trifluoride dimethyl etherate |
| 2988 | EN | Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. |
| 3123 | EN | Poisonous liquid, water-reactive, n.o.s. |
| 3125 | EN | Poisonous solid, water-reactive, n.o.s. |
| 3130 | EN | Water-reactive liquid, poisonous, n.o.s. |
| 3134 | EN | Water-reactive solid, poisonous, n.o.s. |
| 3385 | EN | Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone A) |
| 3386 | EN | Poisonous by inhalation liquid, water-reactive, n.o.s. (Inhalation Hazard Zone B) |
Guide 139 in Spanish and French
| UN/NA | Spanish name (GRE 2024) | French name (GMU 2024) |
|---|---|---|
| UN/NA 1183 | Etildiclorosilano | Éthyldichlorosilane |
| UN/NA 1242 | Metildiclorosilano | Méthyldichlorosilane |
| UN/NA 1295 | Triclorosilano | Trichlorosilane |
| UN/NA 1339 | Heptasulfuro de fósforo, que no contiene fósforo amarillo o blanco | Heptasulfure de phosphore, ne contenant pas de phosphore jaune ou blanc |
| UN/NA 1340 | Pentasulfuro de fósforo, que no contiene fósforo amarillo o blanco | Pentasulfure de phosphore, ne contenant pas de phosphore jaune ou blanc |
| UN/NA 1341 | Sesquisulfuro de fósforo, que no contiene fósforo amarillo o blanco | Sesquisulfure de phosphore, ne contenant pas de phosphore jaune ou blanc |
| UN/NA 1343 | Trisulfuro de fósforo, que no contiene fósforo amarillo o blanco | Trisulfure de phosphore, ne contenant pas de phosphore jaune ou blanc |
| UN/NA 1360 | Fosfuro de calcio | Phosphure de calcium |
| UN/NA 1390 | Amidas de metales alcalinos | Amidures de métaux alcalins |
| UN/NA 1395 | Aluminioferrosilicio, en polvo | Alumino-ferro-silicium en poudre |
| UN/NA 1397 | Fosfuro de aluminio | Phosphure d'aluminium |
| UN/NA 1408 | Ferrosilicio | Ferrosilicium |
| UN/NA 1419 | Fosfuro de magnesio y aluminio | Phosphure de magnésium-aluminium |
| UN/NA 1432 | Fosfuro de sodio | Phosphure de sodium |
| UN/NA 1433 | Fosfuros de estaño (IV) | Phosphures stanniques |
| UN/NA 1714 | Fosfuro de cinc; Fosfuro de zinc | Phosphure de zinc |
| UN/NA 2011 | Fosfuro de magnesio | Phosphure de magnésium |
| UN/NA 2012 | Fosfuro de potasio | Phosphure de potassium |
| UN/NA 2013 | Fosfuro de estroncio | Phosphure de strontium |
| UN/NA 2806 | Nitruro de litio | Nitrure de lithium |
| UN/NA 2830 | Litioferrosilicio | Silico-ferro-lithium |
| UN/NA 2965 | Dimetileterato de trifluoruro de boro | Éthérate diméthylique de trifluorure de bore |
| UN/NA 2988 | Clorosilanos, que reaccionan con el agua, inflamables, corrosivos, n.e.p. | Chlorosilanes, hydroréactifs, inflammables, corrosifs, n.s.a. |
| UN/NA 3123 | Líquido tóxico, que reacciona con el agua, n.e.p. | Liquide toxique, hydroréactif, n.s.a. |
| UN/NA 3125 | Sólido tóxico, que reacciona con el agua, n.e.p. | Solide toxique, hydroréactif, n.s.a. |
| UN/NA 3130 | Líquido que reacciona con el agua, tóxico, n.e.p. | Liquide hydroréactif, toxique, n.s.a. |
| UN/NA 3134 | Sólido que reacciona con el agua, tóxico, n.e.p. | Solide hydroréactif, toxique, n.s.a. |
| UN/NA 3385 | Líquido tóxico por inhalación, hidrorreactivo, n.e.p. (Zona A de Peligro para la Inhalación) | Liquide toxique à l'inhalation, hydroréactif, n.s.a. (Danger par Inhalation Zone A) |
| UN/NA 3386 | Líquido tóxico por inhalación, hidrorreactivo, n.e.p. (Zona B de Peligro para la Inhalación) | Liquide toxique à l'inhalation, hydroréactif, n.s.a. (Danger par Inhalation Zone B) |
Class 4 placards in the ERG 2024 table
ERG 2024 says to use its Table of Markings, Labels and Placards only when the ID number or proper shipping name is not available.
| Class or division | Placard | Guide |
|---|---|---|
| 4.1 · Flammable solids, self-reactive substances and solid desensitized explosives | FLAMMABLE SOLID | Guide 134 |
| 4.2 · Substances liable to spontaneous combustion | SPONTANEOUSLY COMBUSTIBLE | Guide 136 |
| 4.3 · Substances which in contact with water emit flammable gases | DANGEROUS WHEN WET | Guide 139 |
Source: ERG 2024 (U.S. DOT PHMSA, Transport Canada, SICT Mexico), for the initial phase of a transportation incident only. Hazora is not an official ERG publication and is not affiliated with or endorsed by these or any other government agencies.