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Guide 135 · ERG 2024

Guide 135 · Library · ERG 2024

Guides
135
UN/NA
54
Edition
ERG 2024

In ERG 2024, Guide 135 is titled “Substances - Spontaneously Combustible”.

Guide 135 covers 54 UN/NA numbers and 80 material names in ERG 2024. None of them carries the letter P (135P). 6 are highlighted in green and listed in Table 1: UN/NA 1380 (Pentaborane); UN/NA 1384 (Sodium dithionite); UN/NA 1923 (Calcium dithionite); UN/NA 1929 (Potassium dithionite); UN/NA 2004 (Magnesium diamide) and UN/NA 2845 (Ethyl phosphonous dichloride, anhydrous). 4 appear in Table 2 as water-reactive materials that produce toxic gases: UN/NA 1384 (Sodium dithionite: H2S and SO2); UN/NA 1923 (Calcium dithionite: H2S and SO2); UN/NA 1929 (Potassium dithionite: H2S and SO2) and UN/NA 2004 (Magnesium diamide: NH3).

The Spanish edition (GRE 2024) titles this guide “Sustancias - Espontáneamente Combustibles”, and the French edition (GMU 2024) “Substances - Spontanément inflammables”.

Material name

UN/NALanguageMaterial name
1363ENCopra
1369ENp-Nitrosodimethylaniline
1376ENIron oxide, spent
1380ENPentaborane
1382ENPotassium sulfide, anhydrous
1383ENAluminum powder, pyrophoric
1384ENSodium dithionite
1385ENSodium sulfide, anhydrous
1386ENSeed cake, with more than 1.5% oil and not more than 11% moisture
1854ENBarium alloys, pyrophoric
1855ENCalcium, pyrophoric
1923ENCalcium dithionite
1929ENPotassium dithionite
1932ENZirconium scrap
2002ENCelluloid, scrap
2004ENMagnesium diamide
2006ENPlastics, nitrocellulose-based, self-heating, n.o.s.
2008ENZirconium powder, dry
2009ENZirconium, dry, finished sheets, strip or coiled wire
2210ENManeb
2217ENSeed cake, with not more than 1.5% oil and not more than 11% moisture
2318ENSodium hydrosulfide, with less than 25% water of crystallization
2441ENTitanium trichloride, pyrophoric
2545ENHafnium powder, dry
2546ENTitanium powder, dry
2845ENEthyl phosphonous dichloride, anhydrous
2846ENPyrophoric solid, organic, n.o.s.
2870ENAluminum borohydride
2881ENMetal catalyst, dry
2940ENCyclooctadiene phosphines
2968ENManeb, stabilized
3088ENSelf-heating solid, organic, n.o.s.
3100ENOxidizing solid, self-heating, n.o.s.
3127ENSelf-heating solid, oxidizing, n.o.s.
3174ENTitanium disulfide
3183ENSelf-heating liquid, organic, n.o.s.
3186ENSelf-heating liquid, inorganic, n.o.s.
3189ENMetal powder, self-heating, n.o.s.
3190ENSelf-heating solid, inorganic, n.o.s.
3194ENPyrophoric liquid, inorganic, n.o.s.
3200ENPyrophoric solid, inorganic, n.o.s.
3205ENAlkaline earth metal alcoholates, n.o.s.
3254ENTributylphosphane
3255ENtert-Butyl hypochlorite
3313ENOrganic pigments, self-heating
3341ENThiourea dioxide
3342ENXanthates
3391ENOrganometallic substance, solid, pyrophoric
3392ENOrganometallic substance, liquid, pyrophoric
3393ENOrganometallic substance, solid, pyrophoric, water-reactive
3394ENOrganometallic substance, liquid, pyrophoric, water-reactive
3395ENOrganometallic substance, solid, water-reactive
3398ENOrganometallic substance, liquid, water-reactive
3542ENArticles containing a substance liable to spontaneous combustion, n.o.s.

Source: ERG 2024 (U.S. DOT PHMSA, Transport Canada, SICT Mexico), for the initial phase of a transportation incident only. Hazora is not an official ERG publication and is not affiliated with or endorsed by these or any other government agencies.

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